427128
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427128
Aldrich
Gallium(III) chloride
anhydrous, beads, −10 mesh, ≥99.999% trace metals basis
| CAS Number: | 13450-90-3 |
| Linear Formula: | GaCl3 |
| Molecular Weight: | 176.08 |
| EC Number: | 236-610-0 |
| MDL number: | MFCD00011018 |
| PubChem Substance ID: | 24866737 |
Description
| Application | Catalyst for a number of transformations such as the ring opening and recyclization of epoxides or the trimerization of alkynes.1,2 |
| Features and Benefits | Lower-temperature solvothermal techniques using GaCl3 and NaN33 or Li3N4 result in nanocrystalline GaN. |
| Radical mediator and catalyst in a number of organic bond formation reactions.5 | |
| Packaging | 5, 25, 100 g in ampule |
| product is packed in vials |
Properties
| grade | anhydrous |
| vapor pressure | 1 mmHg ( 48 °C) |
| assay | ≥99.999% trace metals basis |
| form | beads |
| particle size | −10 mesh |
| mp | 78 °C(lit.) |
| density | 2.47 g/mL at 25 °C(lit.) |
Safety
| Hazard Codes | C |
| Risk Statements | 14-34 |
| Safety Statements | 26-27-28-36/37/39-45 |
| RIDADR | UN 3260 8/PG 2 |
| WGK Germany | 3 |
| RTECS | LW9100000 |
References
| Cited Reference | 1. Barman, D.C. Synlett, 2440, (2003) |
| 2. Kellogg, R.M. Chemtracts 16, 79, (2003) | |
| 3. Grocholl, L. et al. Chem. Mater. 13, 4290, (2001) | |
| 4. Xie, Y. et al. Science 272, 1926, (1996) | |
| 5. Barman, D. C. Synlett, 2440, (2003) | |
| reference | McMurran, J. Inorg. Chem. 37, 6638, (1998) |
| Kouvetakis, J. Inorg. Chem. 36, 1792, (1997) | |
| Fieser | Fieser 17,140 |
| Corp MSDS 1 (1), 1761:C / RegBook 1 (3), 3323:C / Sax 6, 1470 |
